7
QuizMultiple Choice

Colligative Properties — Quiz

Question 7 • Chemistry

Saline is a solution that contains a certain amount of NaCl and is designed to have the same osmotic pressure as normal blood cells. Doctors often give saline to patients who have lost blood. Which of the following explains why glucose of the same molality cannot attain the same effect as saline?

Answer
A
Osmotic pressure increases with the decrease in the number of particles of solute in the solution. NaCl provides fewer particles per formula unit than glucose does.
B
Each formula unit of NaCl will give two particles because of ionization, but each molecule of glucose dissolves to give only one particle. Osmotic pressure for glucose will be lower than is required.
C
Sodium and chloride ions can pass freely through the membranes of red blood cells, but glucose molecules cannot pass through the membranes.
D
Glucose would not maintain osmotic pressure because on dissociation it forms two particles per formula unit, but NaCl would give only one particle per formula unit. Osmotic pressure is higher when the number of particles decreases.

Explanation

At the same molality, osmotic pressure depends on how many dissolved particles are present. NaCl ionizes into sodium and chloride ions, producing about two particles per formula unit, while glucose dissolves as individual molecules and produces one particle per molecule. Thus, glucose of the same molality has a lower osmotic pressure than saline, so it will not have the same effect. The correct choice is B, “Each formula unit of NaCl will give two particles … but each molecule of glucose … only one particle.”

AI-written and checked against the verified answer.

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