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QuizMultiple Choice

Molecular Geometry

Question 1 • *26-27 CFISD TX-Chemistry A CR

Two molecules have the same molecular geometry but different electron domain geometries. Which combination of atoms and lone pairs around the central atom could describe these molecules?

Answer
A
2 atoms and 2 lone pairs; 3 atoms and 0 lone pairs
B
1 atom and 3 lone pairs; 2 atoms and 1 lone pair
C
3 atoms and 1 lone pair; 3 atoms and 0 lone pairs
D
2 atoms and 2 lone pairs; 2 atoms and 1 lone pair

Explanation

In choice D, both molecules have two atoms bonded to the central atom, so each has a bent molecular geometry. With two lone pairs, the first has four electron domains and a tetrahedral electron-domain geometry; with one lone pair, the second has three electron domains and a trigonal-planar electron-domain geometry. Thus, their molecular geometries match but their electron-domain geometries differ.

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