13
AssignmentMultiple Choice

Oxidizing and Reducing Agents

Question 13 • EDG CHEM ES W/LABS2(P) – Q2_9

Use the standard reduction potential table to predict which reaction will occur spontaneously.

Answer
A
2Fe3+(aq) + 2I–(aq) 2Fe2+(aq) + I2(aq)
B
3Na+(aq) + Cr(s) 3Na(s) + Cr3+(aq)
C
Cu(s) + 2HCl(aq) Cu2+ + 2Cl–(aq) + H2(g)

Explanation

For choice A, Fe³⁺ is reduced to Fe²⁺ (E° = +0.77 V), while I⁻ is oxidized to I₂, the reverse of the I₂ reduction reaction (E° = +0.54 V). Thus E°cell = 0.77 − 0.54 = +0.23 V, so the reaction is spontaneous. The other choices have negative cell potentials as written, so they are not spontaneous under standard conditions.

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